{"id":5121,"date":"2022-07-06T11:09:50","date_gmt":"2022-07-06T03:09:50","guid":{"rendered":"https:\/\/www.xindianchem.com\/?p=5121"},"modified":"2022-07-06T11:14:51","modified_gmt":"2022-07-06T03:14:51","slug":"%e4%b8%96%e7%95%8c%e5%82%ac%e5%8c%96%e5%89%82%e5%89%8d%e6%b2%bf%e6%8a%80%e6%9c%af%e4%bb%8b%e7%bb%8d","status":"publish","type":"post","link":"https:\/\/www.xindianchem.com\/5121.html","title":{"rendered":"\u4e16\u754c\u50ac\u5316\u5242\u524d\u6cbf\u6280\u672f\u4ecb\u7ecd"},"content":{"rendered":"

\u4e16\u754c\u50ac\u5316\u5242\u524d\u6cbf\u6280\u672f\u4ecb\u7ecd<\/span><\/a><\/p>\n

\u6458\u8981\uff1a\u8fd9\u91cc\u7cfb\u7edf\u5730\u4ecb\u7ecd\u4e86\u56fd\u5185\u5916\u591a\u79cd\u50ac\u5316\u5242\u65b0\u6280\u672f\u3001\u65b0\u6750\u6599\u548c\u65b0\u4ea7\u54c1\u53d1\u5c55\u52a8\u6001\u548c\u53d1\u5c55\u8d8b\u52bf\uff0c\u9488\u5bf9\u6211\u56fd\u50ac\u5316\u5242\u6280\u672f\u53d1\u5c55\u73b0\u72b6\uff0c\u5bf9\u50ac\u5316\u5242\u884c\u4e1a\u7684\u53d1\u5c55\u63d0\u51fa\u4e86\u81ea\u5df1\u7684\u89c1\u89e3\u3002<\/span><\/p>\n

1.\u524d\u8a00<\/b><\/strong><\/span><\/p>\n

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\"\"<\/span><\/p>\n

1913\u5e74\uff0c\u94c1\u57fa\u50ac\u5316\u5242\u7684\u95ee\u4e16\u5b9e\u73b0\u4e86\u6c28\u7684\u5408\u6210\uff0c\u4ece\u6b64\u5316\u80a5\u5de5\u4e1a\u5728\u4e16\u754c\u8303\u56f4\u8fc5\u901f\u53d1\u5c55\uff1b20\u4e16\u7eaa50\u5e74\u4ee3\u672b\uff0cZiegler\uff0dNatta\u50ac\u5316\u5242\u5f00\u521b\u4e86\u5408\u6210\u6750\u6599\u5de5\u4e1a\uff1b20\u4e16\u7eaa50\u5e74\u4ee3\u521d\uff0c\u5206\u5b50\u7b5b\u51ed\u501f\u5176\u7279\u6b8a\u7684\u7ed3\u6784\u548c\u6027\u80fd\u5f15\u53d1\u4e86\u50ac\u5316\u9886\u57df\u7684\u4e00\u573a\u53d8\u9769\uff1b20\u4e16\u7eaa70\u5e74\u4ee3\uff0c\u6c7d\u8f66\u5c3e\u6c14\u51c0\u5316\u50ac\u5316\u5242\u5728\u7f8e\u56fd\u5b9e\u73b0\u5de5\u4e1a\u5316\uff0c\u5e76\u5728\u4e16\u754c\u8303\u56f4\u5185\u5f15\u8d77\u4e86\u666e\u904d\u91cd\u89c6\uff1b20\u4e16\u7eaa80\u5e74\u4ee3\uff0c\u91d1\u5c5e\u8302\u50ac\u5316\u5242\u4f7f\u5f97\u805a\u70ef\u70c3\u5de5\u4e1a\u51fa\u73b0\u65b0\u7684\u53d1\u5c55\u673a\u9047\u3002\u76ee\u524d\uff0c\u4eba\u7c7b\u6b63\u9762\u4e34\u7740\u8bf8\u591a\u91cd\u5927\u6311\u6218\uff0c\u5982\uff1a\u8d44\u6e90\u7684\u65e5\u76ca\u51cf\u5c11\uff0c\u9700\u8981\u4eba\u4eec\u5408\u7406\u5f00\u53d1\u3001\u7efc\u5408\u5229\u7528\u8d44\u6e90\uff0c\u5efa\u7acb\u548c\u53d1\u5c55\u8d44\u6e90\u8282\u7ea6\u578b\u519c\u4e1a\u3001\u5de5\u4e1a\u3001\u4ea4\u901a\u8fd0\u8f93\u4ee5\u53ca\u751f\u6d3b\u4f53\u7cfb\uff1b\u7ecf\u6d4e\u53d1\u5c55\u4f7f\u73af\u5883\u6c61\u67d3\u8513\u5ef6\u3001\u81ea\u7136\u751f\u6001\u6076\u5316\uff0c\u8981\u6c42\u5efa\u7acb\u548c\u53d1\u5c55\u7269\u8d28\u5168\u5faa\u73af\u5229\u7528\u7684\u751f\u6001\u4ea7\u4e1a\uff0c\u5b9e\u73b0\u751f\u4ea7\u5230\u5e94\u7528\u7684\u6e05\u6d01\u5316\u3002<\/span><\/p>\n

2.\u56fd\u5916\u50ac\u5316\u5242\u6280\u672f\u53d1\u5c55\u8d8b\u52bf<\/b><\/strong><\/span><\/p>\n

\u7ecf\u8fc7\u957f\u671f\u7684\u53d1\u5c55\uff0c\u50ac\u5316\u5242\u7684\u5e94\u7528\u9886\u57df\u5df2\u8d8b\u5411\u5982\u4e0b\u5c40\u9762\uff1a\u4f20\u7edf\u7684\u77f3\u6cb9\u5316\u5de5\u6280\u672f\u57fa\u672c\u8d8b\u4e8e\u6210\u719f\uff0c\u4f46\u9700\u8981\u65b0\u50ac\u5316\u5242\u4ee5\u6ee1\u8db3\u539f\u6599\u6027\u8d28\u53d8\u5dee\u3001\u4ea7\u54c1\u5347\u7ea7\u6362\u4ee3\u4ee5\u53ca\u65e5\u8d8b\u82db\u523b\u7684\u73af\u4fdd\u8981\u6c42\uff1b\u5929\u7136\u6c14\u5316\u5de5\u548c\u7164\u5316\u5de5\u5728\u7ecf\u6d4e\u4e0a\u8fd8\u4e0d\u80fd\u4e0e\u77f3\u6cb9\u5316\u5de5\u7ade\u4e89\uff0c\u6240\u6d89\u53ca\u7684\u50ac\u5316\u6280\u672f\u6709\u5f88\u5927\u7684\u76f8\u4f3c\u6027\uff1b\u7528\u4e8e\u9ad8\u9644\u52a0\u503c\u5316\u5b66\u54c1\u548c\u836f\u7269\u4e2d\u95f4\u4f53\u5408\u6210\u4e3a\u4e3b\u7684\u7cbe\u7ec6\u5316\u5de5\u50ac\u5316\u6280\u672f\u76f8\u5bf9\u8f83\u4e3a\u5206\u6563\uff0c\u53d1\u5c55\u8fdf\u7f13\uff0c\u76ee\u524d\u6b63\u5728\u5f97\u5230\u52a0\u5f3a\uff1b\u4ee5\u73af\u5883\u6cbb\u7406\u548c\u73af\u5883\u4fdd\u62a4\u4e3a\u76ee\u7684\u50ac\u5316\u6280\u672f\u5f97\u5230\u4e86\u5e7f\u6cdb\u7684\u91cd\u89c6\u3002<\/span><\/p>\n

\u00a0\u636e\u7edf\u8ba1\uff0c\u5168\u4e16\u754c\u77f3\u6cb9\u52a0\u5de5\u7684\u4ea7\u503c\u4e3a940\u591a\u4ebf\u7f8e\u5143\uff0c\u57fa\u672c\u6709\u673a\u5316\u5de5\u548c\u7cbe\u7ec6\u5316\u5de5\u5206\u522b520\u548c480\u4ebf\u7f8e\u5143\u5de6\u53f3\uff0c\u867d\u7136\u5728\u4ea7\u91cf\u4e0a\uff0c\u540e\u4e8c\u8005\u4e4b\u548c\u4f4e\u4e8e\u524d\u8005\uff0c\u4f46\u5176\u4ea7\u503c\u5df2\u8d85\u8fc7\u77f3\u6cb9\u52a0\u5de5\uff0c\u800c\u4e14\u5448\u4e0a\u5347\u8d8b\u52bf\u3002\u65b0\u578b\u50ac\u5316\u5242\u3001\u9ad8\u6548\u50ac\u5316\u53cd\u5e94\u6280\u672f\u548c\u50ac\u5316\u65b0\u6750\u6599\u53ca\u50ac\u5316\u5242\u5236\u5907\u5171\u6027\u6280\u672f\u7684\u521b\u65b0\u662f\u63a8\u52a8\u8fd9\u4e9b\u4ea7\u4e1a\u53d1\u5c55\u7684\u6838\u5fc3\u3002\u5176\u4e2d\uff0c\u73af\u4fdd\u7528\u50ac\u5316\u5de5\u827a\u53ca\u76f8\u5e94\u7684\u65b0\u578b\u50ac\u5316\u5242\u3001\u50ac\u5316\u5242\u5236\u5907\u7cbe\u7ec6\u5316\u7b49\u7684\u53d1\u5c55\u662f\u5173\u952e\uff0c\u4e5f\u662f\u4eca\u540e\u50ac\u5316\u5242\u6280\u672f\u7684\u4e3b\u8981\u53d1\u5c55\u65b9\u5411\u3002<\/span><\/p>\n

\"\"<\/span><\/p>\n

2.1 \u65b0\u578b\u50ac\u5316\u5242\u7684\u5f00\u53d1\u4e0e\u5e94\u7528\u53d1\u5c55\u8fc5\u901f<\/b><\/strong><\/span><\/p>\n

2.1.1 \u70bc\u6cb9\u4e0e\u5316\u5de5\u50ac\u5316\u5242<\/span><\/p>\n

\u65b0\u578b\u3001\u9ad8\u6548\u50ac\u5316\u5242\u7684\u7814\u5236\uff0c\u662f\u77f3\u6cb9\u548c\u5316\u5b66\u5de5\u4e1a\u5b9e\u73b0\u8de8\u8d8a\u5f0f\u53d1\u5c55\u7684\u57fa\u7840\u3002\u8fd1\u5e74\u6765\uff0c\u56fd\u9645\u4e0a\u6709\u5173\u50ac\u5316\u7684\u7814\u7a76\u4e2d\uff0c\u8fd150%\u7684\u5de5\u4f5c\u56f4\u7ed5\u5f00\u53d1\u65b0\u578b\u50ac\u5316\u5242\u5c55\u5f00\uff0c\u4e14\u5bf9\u5176\u91cd\u89c6\u7a0b\u5ea6\u65e5\u76ca\u589e\u52a0\u3002\u53e6\u4e00\u663e\u8457\u7279\u70b9\uff0c\u662f\u65b0\u578b\u50ac\u5316\u5242\u7684\u5f00\u53d1\u4e0e\u73af\u5883\u53cb\u597d\u5bc6\u5207\u8054\u7cfb\uff0c\u5373\u8981\u6c42\u50ac\u5316\u5242\u53ca\u50ac\u5316\u6280\u672f\u751f\u4ea7\u751f\u6d3b\u5fc5\u987b\u54c1\u7684\u540c\u65f6\uff0c\u4ece\u6e90\u5934\u6d88\u9664\u6c61\u67d3\u3002\u56fa\u4f53\u9178\u50ac\u5316\u5242\u662f\u8fd1\u5e74\u6765\u56fd\u9645\u4e0a\u53d1\u5c55\u8d77\u6765\u7684\u4e00\u7c7b\u65b0\u578b\u50ac\u5316\u5242\uff0c\u56e0\u5176\u53ef\u5728\u916f\u5316\u3001\u70f7\u57fa\u5316\u3001\u5f02\u6784\u5316\u7b49\u91cd\u8981\u53cd\u5e94\u4e2d\u66ff\u4ee3\u4f20\u7edf\u50ac\u5316\u5242\uff0c\u5e76\u4ece\u6e90\u5934\u675c\u7edd\u6c61\u67d3\uff0c\u4ece\u800c\u6210\u4e3a\u53d1\u5c55\u52bf\u5934\u4e3a\u5f3a\u52b2\u7684\u4e00\u7c7b\u65b0\u578b\u50ac\u5316\u5242\u3002<\/span><\/p>\n

\u5747\u76f8\u78b1\u50ac\u5316\u5728\u5316\u5b66\u54c1\u5408\u6210\u4e2d\u5360\u6709\u76f8\u5f53\u6bd4\u4f8b\uff0c\u5982\u73af\u6c27\u5316\u7269\u5f00\u73af\u52a0\u6210\u5408\u6210\u8868\u9762\u6d3b\u6027\u5242\u3001\u916f\u4ea4\u6362\u5236\u5907\u7cbe\u7ec6\u5316\u5b66\u54c1\u7b49\uff0c\u4f46\u56e0\u4e25\u91cd\u7684\u6c61\u67d3\u95ee\u9898\u5bf9\u73af\u5883\u9020\u6210\u6076\u52a3\u5f71\u54cd\u3002\u8fd1\u5e74\u6765\uff0c\u4ee5\u56fa\u4f53\u78b1\u66ff\u4ee3\u4f20\u7edf\u6c22\u6c27\u5316\u94a0\u7b49\u6db2\u78b1\u50ac\u5316\u5242\u5df2\u6210\u4e3a\u5fc5\u7136\u7684\u53d1\u5c55\u8d8b\u52bf\u3002<\/span><\/p>\n

\u7531\u4e8e\u5bf9\u50ac\u5316\u5242\u6d3b\u6027\u3001\u7ecf\u6d4e\u3001\u73af\u4fdd\u7684\u8981\u6c42\uff0c\u7164\u6db2\u5316\u50ac\u5316\u5242\u7684\u7814\u7a76\u91cd\u70b9\u5df2\u7ecf\u96c6\u4e2d\u5728\u8d85\u7ec6\u7c92\u5206\u6563\u578b\u94c1\u57fa\u50ac\u5316\u5242\u7684\u5236\u5907\u4e0e\u52a0\u5165\u65b9\u5f0f\u4e0a\uff0c\u4eca\u540e\u7684\u7814\u7a76\u8bfe\u9898\u4ecd\u9700\u5728\u7528\u79bb\u5b50\u4ea4\u6362\u6cd5\u5f15\u5165\u50ac\u5316\u5242\u7684\u65b9\u5f0f\u3001\u76f4\u63a5\u6d78\u6e0d\u65b9\u6cd5\u7684\u6539\u8fdb\u3001\u7eb3\u7c73\u7ea7\u6c27\u5316\u94c1\u548c\u6539\u6027(\u786b\u5316)\u6c27\u5316\u94c1\u7684\u5e94\u7528\u3001\u4f4e\u6d53\u5ea6\u7684\u53ef\u4fc3\u8fdb\u94c1\u57fa\u50ac\u5316\u5242\u6d3b\u6027\u63d0\u9ad8\u7684\u91d1\u5c5e\u7684\u52a0\u5165\u7b49\u65b9\u9762\u505a\u5de5\u4f5c\u3002<\/span><\/p>\n

\u00a0<\/span><\/p>\n

2.1.2 \u6c7d\u8f66\u5c3e\u6c14\u51c0\u5316\u50ac\u5316\u5242<\/span><\/p>\n

\u968f\u7740\u6c7d\u8f66\u53d1\u52a8\u673a\u65b0\u6280\u672f\u7684\u5e94\u7528\u53ca\u73af\u4fdd\u6cd5\u89c4\u7684\u65e5\u76ca\u4e25\u683c\uff0c\u6c7d\u8f66\u5c3e\u6c14\u8f6c\u5316\u50ac\u5316\u5242\u5c06\u5448\u4ee5\u4e0b\u53d1\u5c55\u8d8b\u52bf\u3002\u9996\u5148\uff0c\u4e3a\u63d0\u9ad8\u71c3\u6599\u71c3\u70e7\u6548\u7387\u548c\u51cf\u5c11CO\u6392\u653e\uff0c\u6c7d\u8f66\u53d1\u52a8\u673a\u5c06\u9010\u6e10\u91c7\u7528\u8d2b\u71c3\u6280\u672f\u3002\u636e\u6709\u5173\u62a5\u9053\uff0c\u8be5\u53d1\u52a8\u673a\u6bd4\u5e38\u89c4\u53d1\u52a8\u673a\u7684\u71c3\u6599\u7ecf\u6d4e\u6027\u9ad8\u51fa20%\uff5e25%\u3002\u7531\u4e8e\u6c27\u6c14\u8fc7\u5269\uff0c\u56e0\u800c\u5c06NOX\u8fd8\u539f\u8131\u9664\u5c31\u6210\u4e3a\u4e00\u6280\u672f\u96be\u9898\u3002\u76ee\u524d\u6b63\u5728\u7814\u7a76\u7684\u89e3\u51b3\u65b9\u6848\u5305\u62ecNOX\u6355\u96c6\u3001\u9009\u62e9\u6027\u8fd8\u539f\u548c\u7535\u70ed\u50ac\u5316\u5242\u7b49\uff0c\u8be5\u6280\u672f\u53ef\u671b\u4e8e\u8fd1\u671f\u5728\u6b27\u6d32\u5de5\u4e1a\u5316\u3002\u5176\u6b21\u662f\u8bbe\u8ba1\u53d1\u52a8\u673a\u51b7\u542f\u52a8\u65f6\u80fd\u5feb\u901f\u9884\u70ed\u7684\u50ac\u5316\u5242\u3002<\/span><\/p>\n

\u5728\u6b27\u6d32\u548c\u5317\u7f8e\uff0c\u6c7d\u8f66\u6392\u653e\u6c61\u67d3\u7269\u4e3b\u8981\u662f\u5728\u50ac\u5316\u8f6c\u5316\u5668\u9884\u70ed\u4e4b\u524d\u7684\u65e9\u671f\u6392\u653e\u5f15\u8d77\u7684\u3002\u5728\u4eca\u540e\u6570\u5e74\u4e2d\uff0c\u7f8e\u56fd\u3001\u6b27\u6d32\u548c\u65e5\u672c\u5c06\u751f\u6548\u7684\u66f4\u4e3a\u4e25\u683c\u7684\u6392\u653e\u9650\u5236\u4e3b\u8981\u662f\u9488\u5bf9\u542f\u52a8\u524d20\uff5e30s\u5c3e\u6c14\u7684\u51c0\u5316\u3002\u6b64\u5916\uff0c\u6c7d\u8f66\u5c3e\u6c14\u8f6c\u5316\u50ac\u5316\u5242\u751f\u4ea7\u5546\u6b63\u81f4\u529b\u4e8e\u51cf\u5c11\u50ac\u5316\u5242\u4e2d\u7684\u8d35\u91d1\u5c5e\u542b\u91cf\u3002\u7b2c\u4e09\u662f\u6d88\u9664H2S\u7684\u6392\u653e\u3002<\/span><\/p>\n

\u00a0<\/span><\/p>\n

2.1.3 \u5149\u50ac\u5316\u5242<\/span><\/p>\n

20\u4e16\u7eaa 70\u5e74\u4ee3\u521d\u7684\u77f3\u6cb9\u5371\u673a\u4e0d\u4ec5\u5e26\u6765\u4e86\u5149\u7535\u5316\u5b66\u7684\u8fc5\u901f\u53d1\u5c55\uff0c\u800c\u4e14\u5f15\u8d77\u4e86\u5bf9\u5149\u50ac\u5316\u5242\u9886\u57df\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u8fd1 30\u5e74\u6765\uff0c\u7531\u4e8e\u5728\u73af\u5883\u6cbb\u7406\u3001\u592a\u9633\u80fd\u8f6c\u6362\u3001\u4e34\u5e8a\u533b\u5b66\u7b49\u8bf8\u591a\u65b9\u9762\u7684\u6f5c\u5728\u5e94\u7528\uff0c\u5149\u50ac\u5316\u53ca\u5176\u76f8\u5173\u6280\u672f\u5f97\u5230\u4e86\u5feb\u901f\u53d1\u5c55\uff0c\u5c24\u5176\u5728\u6c61\u6c34\u5904\u7406\u548c\u592a\u9633\u80fd\u8f6c\u6362\u65b9\u9762\u5f97\u5230\u4e86\u5e7f\u6cdb\u7814\u7a76\u3002<\/span><\/p>\n

\u4ece\u5149\u50ac\u5316\u5242\u5e94\u7528\u7684\u524d\u666f\u6765\u770b\uff0c\u76ee\u524d\u4e3b\u8981\u5e94\u7528\u9886\u57df\uff1a\u4e00\u662f\u4e8c\u6c27\u5316\u949b\u6d82\u5c42\u7684\u81ea\u6d01\u51c0\u529f\u80fd\u3002\u5c06\u4e8c\u6c27\u5316\u949b\u9540\u5728\u5efa\u7b51\u6750\u6599\u3001\u4ea4\u901a\u5de5\u5177\u3001\u5ba4\u5185\u88c5\u4fee\u6750\u6599\u7684\u5916\u8868\uff0c\u5229\u7528\u751f\u6d3b\u4e2d\u7684\u592a\u9633\u5149\u3001\u7167\u660e\u706f\u5149\u5373\u80fd\u5206\u89e3\u8fd9\u4e9b\u8868\u5c42\u7684\u6c61\u67d3\u7269\uff0c\u96e8\u6c34\u6e05\u6d17\u5373\u5b9e\u73b0\u81ea\u6d01\u529f\u80fd\u3002\u4e8c\u662f\u8d85\u4eb2\u6c34\u6027\u80fd\u7528\u4e8e\u5236\u5907\u9632\u96fe\u8bbe\u5907\u3002\u5982\u6d82\u6709\u8d85\u4eb2\u6c34\u5149\u50ac\u5316\u6027\u8584\u819c\u7684\u73bb\u7483\u9047\u5230\u6c34\u6c14\u65f6\u8868\u9762\u5f62\u6210\u4e86\u5747\u5300\u7684\u6c34\u819c\uff0c\u6240\u4ee5\u955c\u50cf\u4fdd\u6301\u6e05\u6670\u3002\u4e09\u662f\u7a7a\u6c14\u548c\u6c34\u8d44\u6e90\u7684\u51c0\u5316\u3002<\/span><\/p>\n\n\n\n\n\n
\u4e2d\u6587\u540d<\/b><\/strong><\/span><\/td>\n\u5149\u89e6\u5a92<\/span><\/td>\n\u6240\u5c5e\u5b66\u79d1<\/b><\/strong><\/span><\/td>\n\u5316\u5b66<\/span><\/td>\n<\/tr>\n
\u5916\u6587\u540d<\/b><\/strong><\/span><\/td>\nphotocatalyst\u00a0<\/span><\/td>\n\u4e3b\u8981\u6210\u5206<\/b><\/strong><\/span><\/td>\nN\u578b\u534a\u5bfc\u4f53\u6750\u6599\u00a0<\/span><\/td>\n<\/tr>\n
\u4ee3\u8868\u7269\u8d28<\/b><\/strong><\/span><\/td>\n\u4e8c\u6c27\u5316\u949b<\/span><\/td>\n\u672c \u00a0\u00a0\u00a0\u8d28<\/b><\/strong><\/span><\/td>\n\u5149\u50ac\u5316\u5242\u00a0<\/span><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u00a0<\/span><\/p>\n","protected":false},"excerpt":{"rendered":"

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